What is the mole fraction of a non-volatile solute in …

Chemistry Questions

What is the mole fraction of a non-volatile solute in an aqueous solution with a relative lowering of vapor pressure of 0.0225?

Short Answer

Vapor pressure is crucial for understanding how a non-volatile solute impacts a solvent, leading to the concept of relative lowering of vapor pressure, defined as the decrease in vapor pressure relative to the pure solvent. The mole fraction of the non-volatile solute can be calculated using the formula ŒiP/P‚CA, resulting in a mole fraction of 0.0225 based on given values.

Step-by-Step Solution

Step 1: Understanding Vapor Pressure

The concept of vapor pressure is critical in understanding how a non-volatile solute affects a solvent. Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid phase. In solutions, a non-volatile solute decreases the vapor pressure of the solvent, which is essential for calculating the properties of the solution.

Step 2: Relative Lowering of Vapor Pressure

The relative lowering of vapor pressure is defined as the ratio of the decrease in vapor pressure to the vapor pressure of the pure solvent. This can be represented mathematically as:

  • ≈íiP: lowering of vapor pressure
  • P0: vapor pressure of the pure solvent
  • Xs: mole fraction of the solute

The relationship can be expressed with the equation: ŒiP/P0 = Xs, where Xs represents the mole fraction of the solute.

Step 3: Calculating Mole Fraction of Non-Volatile Solute

To find the mole fraction of the non-volatile solute in your solution, plug in the provided values into the equation. Given the value of the relative lowering of vapor pressure as 0.0225:

  • Xs = ≈íiP/P0 = 0.0225

This directly shows that the mole fraction of the non-volatile solute is 0.0225, which indicates the composition of the solute in the solution effectively.

Related Concepts

Vapor Pressure

Defining the pressure exerted by a vapor in equilibrium with its liquid or solid phase, essential for understanding solvent behavior in solutions

Relative Lowering Of Vapor Pressure

The ratio of the decrease in vapor pressure of a solution to the vapor pressure of the pure solvent, indicating how a solute affects the solvent’s vapor properties

Mole Fraction

The ratio of the number of moles of solute to the total number of moles of all components in the solution, used to calculate the concentration of a solute.

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