What is the activation energy for a gaseous reaction that …

Chemistry Questions

What is the activation energy for a gaseous reaction that triples in rate when the temperature is increased from 17¬∞C to 27¬∞C? [Given: 2.303 R = 19.15 J K‚Aª¬π mol‚Aª¬π, log 3 = 0.48]

Short Answer

To calculate activation energy using the Arrhenius equation, first understand the logarithmic form: log (k2/k1) = Ea / 2.303R (1/T1 – 1/T2). By substituting the provided values and solving, the activation energy is found to be approximately 184,000 J/mol (184 kJ/mol).

Step-by-Step Solution

Step 1: Understand the Arrhenius Equation

The first step in calculating the activation energy is to understand the Arrhenius equation, which relates the rate constants of a reaction at two different temperatures. The logarithmic form of the Arrhenius equation is:

  • log (k2/k1) = Ea / 2.303R (1/T1 – 1/T2)

Here, k1 and k2 are the rate constants at temperatures T1 and T2, respectively, and Ea is the activation energy. We need to gather the values for rate change, temperatures, and the ideal gas constant.

Step 2: Substitute the Values

Next, substitute the known values into the Arrhenius equation. For this problem, the following values are provided:

  • Rate change (k2/k1) = 3 (meaning the rate triples)
  • T1 = 17¬¨‚àûC = 290K
  • T2 = 27¬¨‚àûC = 300K
  • 2.303R = 19.15 J/K mol

Plugging these values into the equation allows us to isolate and solve for Ea. Calculate the temperature term (1/T1 – 1/T2) to facilitate the calculation.

Step 3: Calculate Activation Energy

The final step is to simplify and solve the equation to find the activation energy (Ea). After inserting the calculated values back into the equation:

  • Calculate: log 3 ‚Äöaa 0.48
  • Solve for Ee using your results: 21.155256 / 0.000115

Upon solving, the result will yield an activation energy of approximately 184,000 J/mol, or 184 kJ/mol, indicating the energy required to start this reaction.

Related Concepts

Arrhenius Equation

A mathematical formula that describes the relationship between the rate constants of a chemical reaction and temperature, typically expressed in a logarithmic form to calculate activation energy.

Activation Energy (Ea)

The minimum amount of energy required for a chemical reaction to occur, which can be calculated using the arrhenius equation.

Rate Constant (K)

A numerical value that represents the speed of a reaction at a given temperature, with different rates (k1 and k2) corresponding to different temperatures (t1 and t2).

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